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The Explainer· Kitchen

Is parchment paper toxic? A calm look at the coating, bleaching, and PFAS

A sheet of unbleached brown parchment paper lining a metal baking tray on a pale wood counter beside a folded linen cloth in soft morning light.

By The PlasticFreeLab TeamUpdated July 27, 20269 min read

Baking parchment is coated with silicone, sometimes bleached, and a few cooking papers have contained PFAS. Here is what is actually safe at oven temperatures, and how to pick a parchment worth buying.

The FAQ

What people ask us next.

Is parchment paper toxic?
The reassuring short answer is that ordinary baking parchment is one of the safer things you can line an oven tray with, and for most people it is not a meaningful source of harmful chemicals. Genuine parchment is made by passing paper through a sulfuric acid bath, which gives it a dense, grease-resistant, heat-tolerant surface, and it is then usually coated with a thin layer of food-grade silicone so food releases cleanly. Both parts, the treated paper and the silicone, are regarded as stable and safe for food contact by food-safety agencies at normal baking temperatures. The nuances worth knowing are narrow rather than frightening: some cheaper papers use a coating called Quilon that contains chromium instead of silicone, bleached parchment involves a whitening step some people prefer to skip, and a handful of greaseproof cooking papers have historically carried PFAS. None of those turns a standard sheet of silicone parchment into something dangerous, but they are the reasons it is worth reading what you actually buy, which the questions below take one at a time.
What is the coating on parchment paper, and is silicone safe?
Most quality parchment is coated with food-grade silicone, and this is the coating you want, because silicone is what lets the paper stay non-stick and heat-tolerant without needing anything more concerning. Silicone used for food contact is a synthetic polymer made from silicon and oxygen, and it is widely permitted for cookware and bakeware by food-safety regulators, which is the same reason silicone baking mats and moulds are considered oven-safe. At the temperatures a home oven reaches, a silicone-coated sheet is stable and is not expected to break down into the food. The coating to be more cautious about is Quilon, sometimes listed as a chromium complex, which a few budget parchment brands use instead of silicone; it works, but it introduces chromium into a food-contact surface and can release it when burned, so it is the one worth avoiding by choosing a paper that plainly says silicone-coated or unbleached silicone parchment. If a roll does not say what its coating is, that vagueness is itself the useful signal, in the same way it is with cookware.
Is bleached white parchment worse than unbleached brown?
This is more about preference and process than a clear safety gap, but the distinction is real and easy to act on. Bright white parchment has been bleached, historically with chlorine and now more often with a chlorine-free oxygen process, whereas unbleached parchment is the natural brown colour of the paper and skips the whitening step entirely. The concern people raise about chlorine bleaching is the theoretical formation of trace dioxins, a group of persistent pollutants, during chlorine-based paper processing. In practice the amounts on a modern bleached baking sheet are extremely small and most manufacturers have moved to chlorine-free bleaching, so a white sheet is not a genuine hazard. Even so, the simplest way to sidestep the question is to buy unbleached brown parchment, which performs identically in baking, avoids the bleaching step on principle, and is usually the version sold as the natural or eco option. It is a low-effort choice rather than a fix for a real danger.
Does parchment paper contain PFAS?
Standard silicone baking parchment is not a typical source of PFAS, but the honest answer needs a boundary, because the wider world of greaseproof paper is where PFAS has genuinely turned up. PFAS, the group known as forever chemicals, were for years added to some paper products specifically to make them resist grease, and testing has repeatedly found them in fast-food wrappers, microwave popcorn bags, and certain moulded fibre and greaseproof papers. Baking parchment achieves its grease resistance mainly through the acid treatment of the paper and the silicone coating rather than through a fluorinated coating, which is why reputable parchment is generally not the concern; the concern is loosely marketed greaseproof or non-stick papers that do not say how they resist grease. The practical rule is to choose a product labelled as silicone-coated parchment and, ideally, PFAS-free, and to treat any grease-resistant paper that stays silent about its coating with the same caution you would apply to non-stick cookware. Our guide to PFAS forever chemicals explains why that quiet grease resistance is worth questioning.
Is parchment paper safe at high oven temperatures?
Yes, within the temperature range the manufacturer prints on the box, and staying inside that range is the single most useful habit. Most silicone baking parchment is rated to somewhere around 220 to 230 degrees Celsius, roughly 425 to 450 Fahrenheit, and used below that it browns and crisps food without degrading. The reason the limit matters is not that the paper suddenly becomes toxic one degree above it, but that parchment scorches, darkens, and can eventually char or catch fire if pushed well past its rating or placed under a broiler element, and charred paper is both a fire risk and simply not something you want touching food. So the safe approach is ordinary: keep to the stated temperature, do not use parchment under a direct grill or broiler, and do not let it hang over the edges of the tray near a heating element. Used this way it is stable and does not leave anything meaningful in the food, which is exactly why it is the default liner in professional kitchens.
How do I choose a non-toxic parchment paper?
The choice comes down to three plain checks, and once you know them any supermarket aisle becomes easy to read. First, look for unbleached parchment, the natural brown kind, which skips the whitening step and performs identically to the white version. Second, choose a paper that says it is silicone-coated rather than one that is vague about its coating, so you are getting the stable silicone surface rather than a chromium-based Quilon coating. Third, favour a product that states it is PFAS-free, which rules out the fluorinated grease resistance that has shown up in some greaseproof papers. A roll that ticks all three, unbleached, silicone-coated, PFAS-free, is a genuinely low-concern kitchen staple. If you would rather own something reusable instead of a single-use roll, a silicone baking mat covers most of the same jobs and lasts for years, and for wrapping and storing food our guides to glass food storage and beeswax wraps cover the plastic-free options. The theme is the same one that runs through a non-toxic kitchen: pick the version that tells you what it is made of.
References

Sources we cited on this page.

  1. 01US FDA, Packaging & Food Contact Substances (FCS)
  2. 02US FDA, Silicones as food-contact substances (21 CFR 177.2600)
  3. 03US EPA, Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS)
  4. 04US EPA, Learn about Dioxin
  5. 05NSF/ANSI 51: Food Equipment Materials
About the byline

The PlasticFreeLab Team

A small group of researchers and writers cutting through the noise around non-toxic living. We read the studies, read the labels, test the products. We update our recommendations as the science evolves. We do not accept payment for product placement, we disclose every affiliate relationship, and we name the brands we reject.

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